Issue 28, 2019

MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure

Abstract

This paper presents the first transformation of MOFs to polymers without any additives by using a one-step MOF-templated self-polymerization approach. We investigate the conversion process and demonstrate that the MOF-templated self-polymerization is a new and effective approach for the in situ conversion of organic ligands to polymers and even carbon nanomaterials with maintained MOF configurations.

Graphical abstract: MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure

Supplementary files

Article information

Article type
Communication
Submitted
06 Feb 2019
Accepted
12 Mar 2019
First published
12 Mar 2019

Chem. Commun., 2019,55, 4071-4074

MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure

C. Zhou, A. Li, D. Wang, E. Pan, X. Chen, M. Jia and H. Song, Chem. Commun., 2019, 55, 4071 DOI: 10.1039/C9CC01081E

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