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ABaSbQ3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ3 ligands regulating the magnitudes of birefringences

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Abstract

A new series of ABaSbQ3 compounds (A = Li, Na; Q = S, Se) featuring isolated SbQ3 ligands with different arrangement modes was synthesized. The structural transformations (monoclinic to orthorhombic) in the known A–MII–Sb–Q3 system showing an intimate relationship with the differences (Δd = LIIM–QLA–Q) were systematically investigated for the first time. Remarkably, the diverse arrangement modes of the isolated SbQ3 ligands have also proven effective at regulating the optical anisotropy based on first principles calculation.

Graphical abstract: ABaSbQ3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ3 ligands regulating the magnitudes of birefringences

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Publication details

The article was received on 22 Jan 2019, accepted on 08 Apr 2019 and first published on 08 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC00560A
Citation: Chem. Commun., 2019, Advance Article

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    ABaSbQ3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ3 ligands regulating the magnitudes of birefringences

    A. Abudurusuli, K. Wu, A. Tudi, Z. Yang and S. Pan, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC00560A

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