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Homochiral iron(II)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel

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Abstract

Homochiral iron(II)-based nanotubular metal phosphonates (R)- and (S)-[Fe(pemp)(H2O)2] [pemp2− = (R)- or (S)-(1-phenylethylamino)methylphosphonate] are reported showing metamagnetism at low temperature. The dehydrated product features coordinatively unsaturated and redox-active metal ion sites that enable it to strongly bind nitric oxide at room temperature.

Graphical abstract: Homochiral iron(ii)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel

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Publication details

The article was received on 20 Jan 2019, accepted on 04 Feb 2019 and first published on 08 Feb 2019


Article type: Communication
DOI: 10.1039/C9CC00506D
Citation: Chem. Commun., 2019, Advance Article

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    Homochiral iron(II)-based metal–organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel

    J. Jia, J. Feng, X. Huang, S. Bao and L. Zheng, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC00506D

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