Issue 19, 2019

Visible-light-induced metathesis reaction between diselenide and ditelluride

Abstract

The Se–Te bond was prepared by a metathesis reaction between diselenides and ditellurides, which could be manipulated with the presence or absence of visible light. Additionally, the apparent activation energy of the exchange process was measured to be only 28.01 kJ mol−1, explaining the high reactivity and sensitivity to light.

Graphical abstract: Visible-light-induced metathesis reaction between diselenide and ditelluride

Supplementary files

Article information

Article type
Communication
Submitted
10 Jan 2019
Accepted
06 Feb 2019
First published
06 Feb 2019

Chem. Commun., 2019,55, 2813-2816

Visible-light-induced metathesis reaction between diselenide and ditelluride

C. Liu, J. Xia, S. Ji, Z. Fan and H. Xu, Chem. Commun., 2019, 55, 2813 DOI: 10.1039/C9CC00252A

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