Issue 23, 2019
From the journal:

Chemical Communications

Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex†

Sergii I. Shylin, ORCID logo *a   Mariia V. Pavliuk,a   Luca D’Amario,a   Fikret Mamedov,a   Jacinto Sá,a   Gustav Berggren ORCID logo a  and  Igor O. Fritsky*b  

* Corresponding authors

a Department of Chemistry – Ångström Laboratory, Uppsala University, PO Box 523, 75120 Uppsala, Sweden
E-mail: sergii.shylin@kemi.uu.se

b Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska 64, 01601 Kiev, Ukraine
E-mail: ifritsky@univ.kiev.ua

Abstract

A water-stable FeIV clathrochelate complex catalyses fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s−1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.

Graphical abstract: Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

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Article information

DOI
https://doi.org/10.1039/C9CC00229D
Article type
Communication
Submitted
09 Jan 2019
Accepted
18 Feb 2019
First published
18 Feb 2019
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2019,55, 3335-3338

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Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex

S. I. Shylin, M. V. Pavliuk, L. D’Amario, F. Mamedov, J. Sá, G. Berggren and I. O. Fritsky, Chem. Commun., 2019, 55, 3335 DOI: 10.1039/C9CC00229D

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