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Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(II) complex

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Abstract

Selective reduction of 1,5-diazacyclooctatetraenes with potassium or a Co(I) complex was achieved to provide the first structurally well-defined aromatic 1,5-diazacyclooctatetraenyl dianion or a novel dinuclear Co(II) complex bridged by a bipyrrolinyl dianion, respectively.

Graphical abstract: Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex

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Publication details

The article was received on 04 Jan 2019, accepted on 04 Feb 2019 and first published on 04 Feb 2019


Article type: Communication
DOI: 10.1039/C9CC00075E
Citation: Chem. Commun., 2019, Advance Article

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    Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(II) complex

    Z. Huang, G. Tan, C. Chen, W. Zhang, X. Wang and Z. Xi, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC00075E

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