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Issue 16, 2019
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Catalyst-controlled cascade synthesis of bridged bicyclic tetrahydrobenz[b]azepine-4-ones

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Abstract

A catalyst-controlled cascade reaction has been developed for the synthesis of bridged bicyclic tetrahydrobenz[b]azepin-4-ones from N-arylnitrones and allenes. This method expands the accessible structural diversity of a synthetically challenging heterocyclic scaffold and tunes a catalyst-sensitive process in a new direction.

Graphical abstract: Catalyst-controlled cascade synthesis of bridged bicyclic tetrahydrobenz[b]azepine-4-ones

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Publication details

The article was received on 31 Dec 2018, accepted on 29 Jan 2019 and first published on 30 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC10313E
Citation: Chem. Commun., 2019,55, 2309-2312

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    Catalyst-controlled cascade synthesis of bridged bicyclic tetrahydrobenz[b]azepine-4-ones

    M. A. Kroc, M. Markiewicz, W. H. Pace, D. J. Wink and L. L. Anderson, Chem. Commun., 2019, 55, 2309
    DOI: 10.1039/C8CC10313E

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