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Issue 16, 2019
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Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

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Abstract

A giant, chiral square-shaped octaimine macrocycle has been obtained in a controlled manner from readily available and inexpensive substrates: 9,10-diphenylanthracene-based dialdehyde and trans-1,2-diaminocyclohexane. Reduction of the polyimine led to a chiral octaamine characterized by a very large internal hydrophobic cavity.

Graphical abstract: Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

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Publication details

The article was received on 24 Dec 2018, accepted on 25 Jan 2019 and first published on 25 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC10184A
Citation: Chem. Commun., 2019,55, 2301-2304

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    Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

    M. Zgorzelak, J. Grajewski, J. Gawroński and M. Kwit, Chem. Commun., 2019, 55, 2301
    DOI: 10.1039/C8CC10184A

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