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Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

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Abstract

Various carbonyl-bridged dibenzofulvalenes were synthesized by a sequence of rhodium-catalyzed stitching reaction and post-functionalization, and their optical and electronic properties could be tuned by changing the terminal substituents. The present stitching reaction also allowed for facile synthesis of dibenzofulvalenes having C, Si, Ge, S, and P as the bridging elements.

Graphical abstract: Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

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Publication details

The article was received on 15 Dec 2018, accepted on 28 Dec 2018 and first published on 29 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09943J
Citation: Chem. Commun., 2019, Advance Article
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    Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

    R. Shintani, S. Kishikawa, K. Nakamura, T. Tsuda and K. Nozaki, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09943J

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