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Conductive Nb12O29 hierarchical microspheres with nanosheet shells were synthesized based on a hydrothermal process and a high-temperature hydrogen reduction treatment. The obtained materials demonstrated comprehensively good electrochemical properties, including a significant pseudocapacitive contribution, safe operating potential, high reversible capacity, superior initial coulombic efficiency, increased rate capability, and durable cycling stability.

Graphical abstract: Nanosheet-based Nb12O29 hierarchical microspheres for enhanced lithium storage

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