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Issue 21, 2019
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Multi-colour uranyl emission efficiently tuned by hexacyanidometallates within hybrid coordination frameworks

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Abstract

Unique hybrid organic–inorganic coordination networks, three-dimensional [(UO2)2(OH)(4,4′-bpdo)2][M(CN)6nH2O (M = Co, 1; Rh, 2; Ir, 3) and layered [(UO2)2(OH)2(4,4′-bpdo)2][Pt(CN)6]·H2O (4), employing cyanide, hydroxide and 4,4′-bpdo bridges, are reported. They exhibit vibronically coupled charge transfer emission of uranyl ions, whose colour is tunable from green to orange by the implemented hexacyanidometallates.

Graphical abstract: Multi-colour uranyl emission efficiently tuned by hexacyanidometallates within hybrid coordination frameworks

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Supplementary files

Article information


Submitted
09 Dec 2018
Accepted
21 Jan 2019
First published
21 Jan 2019

Chem. Commun., 2019,55, 3057-3060
Article type
Communication

Multi-colour uranyl emission efficiently tuned by hexacyanidometallates within hybrid coordination frameworks

S. Chorazy, J. J. Zakrzewski, M. Reczyński and B. Sieklucka, Chem. Commun., 2019, 55, 3057
DOI: 10.1039/C8CC09757G

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