Issue 22, 2019
From the journal:

Chemical Communications

Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes†

Priyabrata Ghana, ORCID logo a   Franziska D. van Krüchten,a   Thomas P. Spaniol, ORCID logo a   Jan van Leusen, ORCID logo a   Paul Kögerler ORCID logo a  and  Jun Okuda ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

Abstract

By using a triaryl-Tren ligated titanium dinitrogen complex, K2[{(Xy-N3N)Ti}2(μ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved under ambient conditions with a turnover number (TON) of up to 16.5 per titanium atom.

Graphical abstract: Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes

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Article information

DOI
https://doi.org/10.1039/C8CC09742A
Article type
Communication
Submitted
08 Dec 2018
Accepted
12 Feb 2019
First published
19 Feb 2019

Chem. Commun., 2019,55, 3231-3234

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Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes

P. Ghana, F. D. van Krüchten, T. P. Spaniol, J. van Leusen, P. Kögerler and J. Okuda, Chem. Commun., 2019, 55, 3231 DOI: 10.1039/C8CC09742A

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