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Ligand-modulated ring-expansion

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Abstract

An unstrained palladium-containing macrocycle was expanded by a ring-opening metathesis strategy. This reaction was driven by coordination of a bulky ligand, 2,6-lutidine, to the palladium center, enabling a monometallic macrocycle to transform into a bimetallic dimeric macrocycle.

Graphical abstract: Ligand-modulated ring-expansion

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Publication details

The article was received on 07 Dec 2018, accepted on 07 Jan 2019 and first published on 11 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC09710K
Citation: Chem. Commun., 2019, Advance Article
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    Ligand-modulated ring-expansion

    V. Carta, M. A. Soto and M. J. MacLachlan, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09710K

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