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Abstract | Cited by

An unstrained palladium-containing macrocycle was expanded by a ring-opening metathesis strategy. This reaction was driven by coordination of a bulky ligand, 2,6-lutidine, to the palladium center, enabling a monometallic macrocycle to transform into a bimetallic dimeric macrocycle.

Graphical abstract: Ligand-modulated ring-expansion

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