Issue 17, 2019

A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

Abstract

A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C2-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.

Graphical abstract: A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2018
Accepted
08 Jan 2019
First published
09 Jan 2019

Chem. Commun., 2019,55, 2421-2424

A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

A. Nagai, T. Nakamura and T. Nabeshima, Chem. Commun., 2019, 55, 2421 DOI: 10.1039/C8CC09643K

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