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Issue 9, 2019
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Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion†

Miriding Mutailipu, ORCID logo ‡ab   Min Zhang, ORCID logo ‡a   Hao Li,ab   Xiao Fan,bc   Zhihua Yang, ORCID logo a   Shifeng Jin,c   Gang Wang*c  and  Shilie Pan ORCID logo *a  
Author affiliations

* Corresponding authors

a CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, China

c Research and Development Center for Functional Crystals, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
E-mail: gangwang@iphy.ac.cn

Abstract

Li4Na2CsB7O14 with unique edge-sharing [BO4]5− tetrahedra, an unprecedented [B14O28]14− cluster, and high anisotropic thermal expansion has been obtained under atmospheric pressure conditions, indicating that high pressure is not essential for obtaining edge-sharing [BO4]5− tetrahedra-containing borates. In addition, Li4Na2CsB7O14 may be used as a thermal expansion material.

Graphical abstract: Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

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Article information

https://doi.org/10.1039/C8CC09422E
Submitted
27 Nov 2018
Accepted
24 Dec 2018
First published
26 Dec 2018
Chem. Commun., 2019,55, 1295-1298
Article type
Communication
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Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

M. Mutailipu, M. Zhang, H. Li, X. Fan, Z. Yang, S. Jin, G. Wang and S. Pan, Chem. Commun., 2019, 55, 1295
DOI: 10.1039/C8CC09422E

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