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Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

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Abstract

Li4Na2CsB7O14 with unique edge-sharing [BO4]5− tetrahedra, an unprecedented [B14O28]14− cluster, and high anisotropic thermal expansion has been obtained under atmospheric pressure conditions, indicating that high pressure is not essential for obtaining edge-sharing [BO4]5− tetrahedra-containing borates. In addition, Li4Na2CsB7O14 may be used as a thermal expansion material.

Graphical abstract: Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

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Publication details

The article was received on 27 Nov 2018, accepted on 24 Dec 2018 and first published on 26 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09422E
Citation: Chem. Commun., 2019, Advance Article
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    Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

    M. Mutailipu, M. Zhang, H. Li, X. Fan, Z. Yang, S. Jin, G. Wang and S. Pan, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09422E

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