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Issue 13, 2019
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Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

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Abstract

A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono- and double-decarbonylations, which gave thioesters and thioethers, respectively, were selectively achieved by changing the ligand. A fundamental study of Ni-catalyzed decarbonylation of α-ketothioesters is presented.

Graphical abstract: Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

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Article information


Submitted
24 Nov 2018
Accepted
16 Jan 2019
First published
17 Jan 2019

Chem. Commun., 2019,55, 1907-1910
Article type
Communication

Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

Z. Zheng, C. Jiang, P. Shao, W. Liu, T. Zhao, P. Xu and H. Wei, Chem. Commun., 2019, 55, 1907
DOI: 10.1039/C8CC09352K

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