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Issue 17, 2019
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Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

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Abstract

For the first time, functional carboxylic acid (–COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by modifiable wettability via a facile mechanochemical reaction. The interior –COOH groups lead to high thermal stability unusual to hybrid-layer structures and undergo the intriguingly reversible nano-morphological transformation never unveiled in metal oxysalts before.

Graphical abstract: Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

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Publication details

The article was received on 22 Nov 2018, accepted on 21 Dec 2018 and first published on 21 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09289C
Citation: Chem. Commun., 2019,55, 2429-2432

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    Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

    L. Hung, H. Yi, Y. Shih, C. Lin and S. Wang, Chem. Commun., 2019, 55, 2429
    DOI: 10.1039/C8CC09289C

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