Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Ling-I Hung; Hsiang-Yi Yi; Yu-Chieh Shih; Chia-Her Lin; Sue-Lein Wang

doi:10.1039/C8CC09289C

Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Ling-I Hung,^a Hsiang-Yi Yi,^a Yu-Chieh Shih,^a Chia-Her Lin^b and Sue-Lein Wang*^a^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, National Tsing Hua University No. 101, Section 2, Kuang-Fu Road, Hsinchu 30013, Taiwan
E-mail: slwang@mx.nthu.edu.tw

^b Department of Chemistry, Chung-Yuan Christian University, Chungli, Taiwan

Abstract

For the first time, functional carboxylic acid (–COOH) groups protruding on both sides of zincophosphate sheets are prepared, leading to a unique surface-active lamellar material characterized by modifiable wettability via a facile mechanochemical reaction. The interior –COOH groups lead to high thermal stability unusual to hybrid-layer structures and undergo the intriguingly reversible nano-morphological transformation never unveiled in metal oxysalts before.

Supplementary files

Publication details

The article was received on 22 Nov 2018, accepted on 21 Dec 2018 and first published on 21 Dec 2018

Article type: Communication

DOI: 10.1039/C8CC09289C

Citation: Chem. Commun., 2019,55, 2429-2432

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Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

L. Hung, H. Yi, Y. Shih, C. Lin and S. Wang, Chem. Commun., 2019, 55, 2429
DOI: 10.1039/C8CC09289C
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Chemical Communications

Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

Abstract

Supplementary files

Publication details

Carboxylic acid-protruding zincophosphate sheets exhibiting surface mechanochemical reactivity and intriguing nano-morphological reversibility

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