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Issue 5, 2019
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Sequence isomeric giant surfactants with distinct self-assembly behaviors in solution

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Abstract

We have designed and synthesized a pair of sequence isomeric giant surfactants based on polystyrene (PS) and polyhedral oligomeric silsesquioxane (POSS) nanoparticles. Although these two macromolecules possess identical compositions as “sequence isomers”, the distinctly arranged POSS sequences lead to different molecular packing conformations, and further induce distinguished self-assembly behaviors in DMF/water solutions.

Graphical abstract: Sequence isomeric giant surfactants with distinct self-assembly behaviors in solution

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Article information


Submitted
20 Nov 2018
Accepted
08 Dec 2018
First published
10 Dec 2018

Chem. Commun., 2019,55, 636-639
Article type
Communication
Author version available

Sequence isomeric giant surfactants with distinct self-assembly behaviors in solution

W. Zhang, W. Shan, S. Zhang, Y. Liu, H. Su, J. Luo, Y. Xia, T. Li, C. Wesdemiotis, T. Liu, H. Cui, Y. Li and S. Z. D. Cheng, Chem. Commun., 2019, 55, 636
DOI: 10.1039/C8CC09207A

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