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Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6

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Abstract

Iridium–hydrido complexes bearing a hemilabile silyl–pyridine–amine pincer ligand were synthesised. They were found to catalyse Si–H deuteration of trialkylsilanes with excess benzene-d6 in 99–94% conversion at room temperature through C–D bond activation and H/D exchange.

Graphical abstract: Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6

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Publication details

The article was received on 19 Nov 2018, accepted on 14 Dec 2018 and first published on 20 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09178A
Citation: Chem. Commun., 2019, Advance Article
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    Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6

    T. Komuro, T. Osawa, R. Suzuki, D. Mochizuki, H. Higashi and H. Tobita, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09178A

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