Photochemical CO2 reduction with mononuclear and dinuclear rhenium catalysts bearing a pendant anthracene chromophore†
Nalaka P.
Liyanage, 
a
Weiwei
Yang,
a
Sayontani
Sinha Roy,
a
Russel H.
Schmehl,
*b
Jared H.
Delcamp
*a
and
Jonah W.
Jurss
*a
a
Weiwei
Yang,
a
Sayontani
Sinha Roy,
a
Russel H.
Schmehl,
*b
Jared H.
Delcamp
*a
and
Jonah W.
Jurss
*a
Abstract
A series of anthracene-substituted mononuclear and dinuclear rhenium complexes have been studied for photocatalytic CO2 reduction. The effects on catalytic activity of one versus two covalently-linked active sites, their relative proximity to one another, and the pendant organic chromophore are discussed.
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