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Copper-Catalyzed Aminothiolation of Terminal Alkynes with Tunable Regioselectivity

Abstract

A simple, mild, and efficient catalytic aminothiolation of terminal alkynes for the synthesis of both 2- and 3-substituted thiazolo[3,2-a]benzimidazoles is established under the catalysis of copper (I), in which complementary regioselectivities could be achieved by using sterically different phenanthroline-based ligands.

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Publication details

The article was received on 16 Nov 2018, accepted on 26 Dec 2018 and first published on 02 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC09122F
Citation: Chem. Commun., 2019, Accepted Manuscript
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    Copper-Catalyzed Aminothiolation of Terminal Alkynes with Tunable Regioselectivity

    Y. Xia, J. Kuang, A. Yang, H. Zhang, C. Su and D. Lee, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C8CC09122F

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