Jump to main content
Jump to site search


Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

Author affiliations

Abstract

A palladium-catalyzed oxidative borylation reaction of conjugated enynones is developed. This reaction represents a new method for the synthesis of furyl-substituted alkenylboronates. The reaction works well with a series of conjugated enynones. Boryl migratory insertion of the palladium carbene intermediate is proposed as the key step in these transformations.

Graphical abstract: Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Nov 2018, accepted on 24 Nov 2018 and first published on 26 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC09024F
Citation: Chem. Commun., 2019, Advance Article
  •   Request permissions

    Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

    Y. Ping, T. Chang, K. Wang, J. Huo and J. Wang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09024F

Search articles by author

Spotlight

Advertisements