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Issue 16, 2019
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Halogen bonding effects on the outcome of reactions at metal centres

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Abstract

Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr–I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.

Graphical abstract: Halogen bonding effects on the outcome of reactions at metal centres

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Article information


Submitted
07 Nov 2018
Accepted
30 Jan 2019
First published
31 Jan 2019

Chem. Commun., 2019,55, 2380-2383
Article type
Communication

Halogen bonding effects on the outcome of reactions at metal centres

L. Carreras, J. Benet-Buchholz, A. Franconetti, A. Frontera, P. W. N. M. van Leeuwen and A. Vidal-Ferran, Chem. Commun., 2019, 55, 2380
DOI: 10.1039/C8CC08884E

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