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Exploring Ligand Non-Innocence of Coordinatively-Versatile Diamidodipyrrinato Cobalt Complexes

Abstract

The non-innocence of diamidodipyrrin is explored in a series of cobaltous complexes with novel binding motifs. By varying the coordination modes, a reversible one-electron reduction is remarkably shifted by nearly 200 mV in a single metal-ligand platform. Our study illustrates a new strategy for modifying the redox activity of porphyrin-like scaffolds.

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Publication details

The article was received on 30 Oct 2018, accepted on 30 Dec 2018 and first published on 02 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC08674E
Citation: Chem. Commun., 2019, Accepted Manuscript
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    Exploring Ligand Non-Innocence of Coordinatively-Versatile Diamidodipyrrinato Cobalt Complexes

    S. S. Saund, S. L. Goldschmid, K. Ng, V. J. Stewart, M. A. Siegler and V. S. Thoi, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C8CC08674E

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