Issue 8, 2019
From the journal:

Chemical Communications

Radio frequency alternating electromagnetic field enhanced tetraruthenium polyoxometalate electrocatalytic water oxidation†

Shuntaro Tsubaki, ORCID logo *a   Shogo Hayakawa,a   Tadaharu Ueda,b   Satoshi Fujii, ORCID logo ac   Ei-ichi Suzuki,a   Jie Zhang, ORCID logo d   Alan Bondd  and  Yuji Wadaa  

* Corresponding authors

a School of Materials and Chemical Technology, Tokyo Institute of Technology, Ookayama 2-12-1 E4-3, Meguro, Tokyo, Japan
E-mail: tsubaki.s.aa@m.titech.ac.jp

b Department of Marine Resource Science, Faculty of Agriculture and Marine Science, Kochi University, Monobe-otsu 200, Nankoku, Japan

c Department of Information and Communication Systems Engineering, Okinawa National College of Technology, 905 Henoko, Nago-shi, Okinawa 905-2192, Japan

d School of Chemistry, Monash University, Clayton, Victoria 3800, Australia

Abstract

Application of radio frequency (RF) electromagnetic waves enhances the electrocatalytic water oxidation by protonated tetraruthenium polyoxometalate ([Ru4(μ-O)4(μ-OH)2(H2O)4(γ-SiW10O36)2]10−). In particular, an enhancement factor of 3.6 is achieved when the level of proton substitution of protonated tetraruthenium polyoxometalate is changed from zero to 9 under application of RF at 200 MHz.

Graphical abstract: Radio frequency alternating electromagnetic field enhanced tetraruthenium polyoxometalate electrocatalytic water oxidation

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Article information

DOI
https://doi.org/10.1039/C8CC07642A
Article type
Communication
Submitted
22 Sep 2018
Accepted
22 Nov 2018
First published
23 Nov 2018

Chem. Commun., 2019,55, 1032-1035

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Radio frequency alternating electromagnetic field enhanced tetraruthenium polyoxometalate electrocatalytic water oxidation

S. Tsubaki, S. Hayakawa, T. Ueda, S. Fujii, E. Suzuki, J. Zhang, A. Bond and Y. Wada, Chem. Commun., 2019, 55, 1032 DOI: 10.1039/C8CC07642A

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