Jump to main content
Jump to site search


A spin crossover porous hybrid architecture for potential sensing applications

Author affiliations

Abstract

Spin crossover cations have been successfully synthesized in the pores of a mesoporous robust Metal–Organic Framework (MOF) MIL-100(Al) through sequential introduction of Fe(III) cations and a sal2trien ligand. The MIL-100(Al)@Fe(sal2trien) hybrid material retains its crystallinity and partial porosity compared to the parent MOF. The spin state of the Fe(sal2trien)+ cations can be modulated at room temperature through sorption of guest molecules, paving the way to the design of a new generation of sensors based on MOF@spin crossover complex solids.

Graphical abstract: A spin crossover porous hybrid architecture for potential sensing applications

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Sep 2018, accepted on 27 Nov 2018 and first published on 28 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07573E
Citation: Chem. Commun., 2019, Advance Article
  •   Request permissions

    A spin crossover porous hybrid architecture for potential sensing applications

    A. Tissot, X. Kesse, S. Giannopoulou, I. Stenger, L. Binet, E. Rivière and C. Serre, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC07573E

Search articles by author

Spotlight

Advertisements