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The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(IV) compounds

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Abstract

Perovskite-derived hybrid platinum iodides with the general formula A2PtIVI6 (A = formamidinium FA and guanidinium GUA) accommodate excess I2 to yield hydrogen-bond-stabilized compounds where the I2 forms catenates with Iāˆ’ anions on the PtI6 octahedra.

Graphical abstract: The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(iv) compounds

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The article was received on 18 Sep 2018, accepted on 19 Nov 2018 and first published on 27 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07536K
Citation: Chem. Commun., 2019, Advance Article
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    The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(IV) compounds

    H. A. Evans, J. L. Andrews, D. H. Fabini, M. B. Preefer, G. Wu, A. K. Cheetham, F. Wudl and R. Seshadri, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC07536K

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