Jump to main content
Jump to site search

Issue 6, 2019
Previous Article Next Article

Annulating thiazolium cations via a direct double C–H activation strategy: Rh–N,S-heterocyclic carbene is the key

Author affiliations

Abstract

Herein we show how metal–N,S-heterocyclic carbene intermediates are conveniently generated and utilized for the first time to construct N,S doubly-doped cationic conjugated tricyclic organic molecules which exhibit tuneable emission. The chemistry proceeds via direct double C–H activation followed by an annulative π-extension pathway.

Graphical abstract: Annulating thiazolium cations via a direct double C–H activation strategy: Rh–N,S-heterocyclic carbene is the key

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Sep 2018, accepted on 14 Dec 2018 and first published on 14 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC07531J
Citation: Chem. Commun., 2019,55, 854-857
  •   Request permissions

    Annulating thiazolium cations via a direct double C–H activation strategy: Rh–N,S-heterocyclic carbene is the key

    C. Dutta, A. B. Sainaba and J. Choudhury, Chem. Commun., 2019, 55, 854
    DOI: 10.1039/C8CC07531J

Search articles by author

Spotlight

Advertisements