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An exceptionally stable Zr-based fluorescent metal–organic framework for highly selective detection of pH

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Abstract

In this study, we synthesized metal–organic frameworks (MOFs) UiO-67-bpydc using H2bpydc as ligands and Zr6 clusters as vertexes. Due to the protonation of the bipyridine group, UiO-67-bpydc shows pH-dependent fluorescence (365 nm/530 nm) in the pH range from 1 to 9, which shows its feasibility as a wide-range pH sensor. Further study indicated that UiO-67-bpydc exhibits stability, reusability, selectivity and has an excellent linear relationship in the pH range 4.0–6.5, and the mechanism of the UiO-67-bpydc fluorescence intensity with the variation of pH has been studied in detail. This MOF-based fluorescent sensor has been applied to specifically detect the pH of solutions in the presence of the body fluid matrix. Compared with reported pH-MOF sensors, UiO-67-bpydc can be practically applied in real samples and is easily prepared with excellent stability in different buffer solutions.

Graphical abstract: An exceptionally stable Zr-based fluorescent metal–organic framework for highly selective detection of pH

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Publication details

The article was received on 12 Sep 2018, accepted on 21 Nov 2018 and first published on 23 Nov 2018


Article type: Paper
DOI: 10.1039/C8AY01998C
Citation: Anal. Methods, 2019, Advance Article
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    An exceptionally stable Zr-based fluorescent metal–organic framework for highly selective detection of pH

    S. Wu, S. Wang, W. Fang, X. Guo and H. Wang, Anal. Methods, 2019, Advance Article , DOI: 10.1039/C8AY01998C

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