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Issue 10, 2019
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SnO2–Ti3C2 MXene electron transport layers for perovskite solar cells

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Abstract

MXenes, a class of two-dimensional (2D) transition metal carbides and nitrides, have a wide range of potential applications due to their unique electronic, optical, plasmonic, and other properties. Herein, we explore the use of the Ti3C2 MXene in organic–inorganic lead halide perovskite solar cells (PSCs). SnO2–Ti3C2 MXene nanocomposites with different contents of Ti3C2 (0, 0.5, 1.0, 2.0, and 2.5 wt‰) were used as electron transport layers (ETLs) in low-temperature processed planar-structured PSCs. Mixing SnO2 with 1.0 wt‰ Ti3C2 effectively increases the power conversion efficiency (PCE) from 17.23% to 18.34%, whereas the device prepared with pristine Ti3C2 as the ETL achieves a PCE of 5.28%. Photoluminescence and electrochemical impedance spectroscopy results reveal that metallic Ti3C2 MXene nanosheets provide superior charge transfer paths, enhancing electron extraction, electron mobility, and decreasing the electron transfer resistance at the ETL/perovskite interface, and thus leading to higher photocurrents. This work proposes a new field of application for MXenes and a promising method to increase the efficiency of solar cells.

Graphical abstract: SnO2–Ti3C2 MXene electron transport layers for perovskite solar cells

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Supplementary files

Article information


Submitted
16 Dec 2018
Accepted
03 Feb 2019
First published
05 Feb 2019

J. Mater. Chem. A, 2019,7, 5635-5642
Article type
Paper

SnO2–Ti3C2 MXene electron transport layers for perovskite solar cells

L. Yang, Y. Dall'Agnese, K. Hantanasirisakul, C. E. Shuck, K. Maleski, M. Alhabeb, G. Chen, Y. Gao, Y. Sanehira, A. K. Jena, L. Shen, C. Dall'Agnese, X. Wang, Y. Gogotsi and T. Miyasaka, J. Mater. Chem. A, 2019, 7, 5635
DOI: 10.1039/C8TA12140K

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