Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.

Issue 2, 2019
Previous Article Next Article

Diffusiophoresis in ionic surfactants: effect of micelle formation

Author affiliations


We explore the consequences of micelle formation for diffusiophoresis of charged colloidal particles in ionic surfactant concentration gradients, using a quasi-chemical association model for surfactant self assembly. The electrophoretic contribution to diffusiophoresis is determined by re-arranging the Nernst–Planck equations, and the chemiphoretic contribution is estimated by making plausible approximations for the density profiles in the electrical double layer surrounding the particle. For sub-micellar solutions we find that a particle will typically be propelled down the concentration gradient, although electrophoresis and chemiphoresis are finely balanced and the effect is sensitive to the detailed parameter choices and simplifying assumptions in the model. Above the critical micelle concentration (CMC), diffusiophoresis becomes much weaker and may even reverse sign, due to the fact that added surfactant goes into building micelles and not augmenting the monomer or counterion concentrations. We present detailed calculations for sodium dodecyl sulfate (SDS), finding that the typical drift speed for a colloidal particle in a ∼100 μm length scale SDS gradient is ∼1 μm s−1 below the CMC, falling to ≲0.2 μm s−1 above the CMC. These predictions are broadly in agreement with recent experimental work.

Graphical abstract: Diffusiophoresis in ionic surfactants: effect of micelle formation

Back to tab navigation

Article information

19 Jul 2018
18 Nov 2018
First published
28 Nov 2018

Soft Matter, 2019,15, 278-288
Article type
Author version available

Diffusiophoresis in ionic surfactants: effect of micelle formation

P. B. Warren, S. Shin and H. A. Stone, Soft Matter, 2019, 15, 278
DOI: 10.1039/C8SM01472H

Social activity

Search articles by author