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Issue 31, 2019
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Mild synthesis of diboryldiborenes by diboration of B–B triple bonds

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Abstract

A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.

Graphical abstract: Mild synthesis of diboryldiborenes by diboration of B–B triple bonds

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Supplementary files

Article information


Submitted
24 May 2019
Accepted
08 Jun 2019
First published
11 Jun 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 7375-7378
Article type
Edge Article

Mild synthesis of diboryldiborenes by diboration of B–B triple bonds

T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller and H. Braunschweig, Chem. Sci., 2019, 10, 7375
DOI: 10.1039/C9SC02544H

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