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Issue 18, 2019
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Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

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Abstract

Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts on the isolation of stable p-block element radicals particularly those involving aluminum, silicon, and phosphorus.

Graphical abstract: Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

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Article information


Submitted
19 Mar 2019
Accepted
06 Apr 2019
First published
08 Apr 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 4727-4741
Article type
Minireview

Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

S. Kundu, S. Sinhababu, V. Chandrasekhar and H. W. Roesky, Chem. Sci., 2019, 10, 4727
DOI: 10.1039/C9SC01351B

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