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Issue 52, 2019, Issue in Progress
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Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

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Abstract

This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance Cu/Zn complexes.

Graphical abstract: Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

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Publication details

The article was received on 03 Sep 2019, accepted on 09 Sep 2019 and first published on 26 Sep 2019


Article type: Paper
DOI: 10.1039/C9RA07055A
RSC Adv., 2019,9, 30541-30544
  • Open access: Creative Commons BY-NC license
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    Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

    D. M. Knoll, T. B. Wiesner, S. M. Marschner, Z. Hassan, P. Weis, M. Kappes, M. Nieger and S. Bräse, RSC Adv., 2019, 9, 30541
    DOI: 10.1039/C9RA07055A

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