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Issue 50, 2019, Issue in Progress
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Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids

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Abstract

In this work we combined kinetic studies for aqueous-phase glucose oxidation in a high-pressure autoclave setup with catalyst reoxidation studies in a liquid-core waveguide membrane reactor. Hereby, we investigated the influence of Nb- and Ta-doping on Mo-based Keggin-polyoxometalates for both reaction steps independently. Most importantly, we could demonstrate a significant increase of glucose oxidation kinetics by Ta- and especially Nb-doping by factors of 1.1 and 1.5 compared to the classical HPA-Mo. Moreover, activation energies for the substrate oxidation step could be significantly reduced from around 80 kJ mol−1 for the classical HPA-Mo to 61 kJ mol−1 for the Ta- and 55 kJ mol−1 for the Nb-doped species, respectively. Regarding catalyst reoxidation kinetics, the doping did not show significant differences between the different catalysts.

Graphical abstract: Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids

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Publication details

The article was received on 18 Jul 2019, accepted on 11 Sep 2019 and first published on 17 Sep 2019


Article type: Paper
DOI: 10.1039/C9RA05544D
RSC Adv., 2019,9, 29347-29356
  • Open access: Creative Commons BY-NC license
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    Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids

    D. Voß, S. Ponce, S. Wesinger, B. J. M. Etzold and J. Albert, RSC Adv., 2019, 9, 29347
    DOI: 10.1039/C9RA05544D

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