Issue 14, 2019

Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

Abstract

The synthesis and characterization of a bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2] and its reactions with a variety of activated heteroaryl bromides, chlorides and iodides were described. These results showed that complex [Ph4P]+[Cu(CF3)2] can serve as a trifluoromethylating reagent.

Graphical abstract: Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]−: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

Supplementary files

Article information

Article type
Research Article
Submitted
18 Apr 2019
Accepted
11 May 2019
First published
13 May 2019

Org. Chem. Front., 2019,6, 2324-2328

Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

H. Liu and Q. Shen, Org. Chem. Front., 2019, 6, 2324 DOI: 10.1039/C9QO00527G

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