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Issue 7, 2019
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Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

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Abstract

Regioselective azotization or bis(amination) products of the title porphyrinoid were achieved in one-pot one-step syntheses under mild conditions using a selection of aromatic amines and isoamyl nitrite or p-chloranil, respectively. Structures, tautomery, chirality as well as spectroscopic and redox properties of the new systems were discussed.

Graphical abstract: Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

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Submitted
07 Jan 2019
Accepted
11 Feb 2019
First published
12 Feb 2019

Org. Chem. Front., 2019,6, 908-918
Article type
Research Article

Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

D. Ren, B. Liu, X. Li, S. Koniarz, M. Pawlicki and P. J. Chmielewski, Org. Chem. Front., 2019, 6, 908
DOI: 10.1039/C9QO00024K

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