Issue 6, 2019

B2pin2-catalyzed oxidative cleavage of a C[double bond, length as m-dash]C double bond with molecular oxygen

Abstract

B2pin2-catalyzed oxidative cleavage of the C[double bond, length as m-dash]C double bond of an olefin with molecular oxygen as the oxidant and oxygen source has been developed. Various diaryl ketone, diketone, triketone and estrone derivatives were obtained in moderate to excellent yields. The NMP (N-methyl pyrrolidone)-stabilized B-centered radical species was proposed as a possible catalyst.

Graphical abstract: B2pin2-catalyzed oxidative cleavage of a C [[double bond, length as m-dash]] C double bond with molecular oxygen

Supplementary files

Article information

Article type
Research Article
Submitted
27 Dec 2018
Accepted
03 Feb 2019
First published
06 Feb 2019

Org. Chem. Front., 2019,6, 841-845

B2pin2-catalyzed oxidative cleavage of a C[double bond, length as m-dash]C double bond with molecular oxygen

Z. Cheng, W. Jin and C. Liu, Org. Chem. Front., 2019, 6, 841 DOI: 10.1039/C8QO01412D

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