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Issue 37, 2019
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Grignard synthesis of fluorinated nanoporous element organic frameworks based on the heteroatoms P, B, Si, Sn and Ge

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Abstract

We present the synthesis and characterization of fluorinated polymers based on P, B, Si, Sn and Ge as heteroatoms via Grignard activation. The polymers are microporous with hydrophobic surfaces. The borate-based polymer was successfully applied as solid acid catalyst in the esterification of acetic acid with ethanol.

Graphical abstract: Grignard synthesis of fluorinated nanoporous element organic frameworks based on the heteroatoms P, B, Si, Sn and Ge

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Article information


Submitted
07 Aug 2019
Accepted
22 Aug 2019
First published
22 Aug 2019

Polym. Chem., 2019,10, 5032-5036
Article type
Communication

Grignard synthesis of fluorinated nanoporous element organic frameworks based on the heteroatoms P, B, Si, Sn and Ge

A. Kann, A. J. D. Krüger, M. Rose and P. J. C. Hausoul, Polym. Chem., 2019, 10, 5032
DOI: 10.1039/C9PY01193E

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