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Issue 6, 2019
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Applications of N′-monofunctionalised TsDPEN derivatives in asymmetric catalysis

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Abstract

This review contains an account of recent developments in the applications of N′-monoalkylated or N′-mono(thio)acylated(N-sulfonyl)-1,2-diphenylethylene-1,2-diamine (TsDPEN) derivatives to asymmetric catalysis. The coverage features examples of applications of derivatives as ligands in organometallic complexes for use in asymmetric reduction and oxidation reactions. The use of TsDPEN derivatives as catalysts in a diverse range of C–C and C–S bond formation reactions is also described in detail.

Graphical abstract: Applications of N′-monofunctionalised TsDPEN derivatives in asymmetric catalysis

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Publication details

The article was received on 19 Nov 2018, accepted on 02 Jan 2019 and first published on 04 Jan 2019


Article type: Review Article
DOI: 10.1039/C8OB02889C
Org. Biomol. Chem., 2019,17, 1301-1321

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    Applications of N′-monofunctionalised TsDPEN derivatives in asymmetric catalysis

    J. Barrios-Rivera, Y. Xu and M. Wills, Org. Biomol. Chem., 2019, 17, 1301
    DOI: 10.1039/C8OB02889C

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