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Issue 21, 2019
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Energy framework approach to the supramolecular reactions: interplay of the secondary bonding interaction in Ph2E2 (E = Se, Te)/p-I-C6F4-I co-crystals

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Abstract

In the co-crystals of diphenyl dichalcogenides Ph2E2 (E = Se, Te), the E–E and E–π(Ph) chalcogen bonds assemble Ph2E2 molecules into the chains, which imitate the typical packing patterns of the parent Ph2E2 crystals. These co-crystals consist of quite stable tectonic 1D and 2D Ph2E2 chain architectures, which are repeated in the crystals of pure Ph2E2 as well as in their co-crystals with the halogen bond donor molecules. These chains can be clearly visualized as separate parallel 1D and 2D structures in the energy framework diagrams in CrystalExplorer. From this point of view, the supramolecular reaction of Ph2E2 with the halogen bond donor 1,4-diiodotetrafluorobenzene (p-DITFB) can be considered as the insertion of p-DITFB molecules between the Ph2E2 chains in such a way that I–E and I–π(Ph) halogen bonds come in place of E–E and Te–π(Ph) chalcogen bonds, which are responsible for the close packing of these chains in the parent crystal form. Persistent packing patterns found in parent and binary crystals can provide insight into the mechanism of the crystallization process.

Graphical abstract: Energy framework approach to the supramolecular reactions: interplay of the secondary bonding interaction in Ph2E2 (E = Se, Te)/p-I-C6F4-I co-crystals

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Publication details

The article was received on 20 Jan 2019, accepted on 15 Apr 2019 and first published on 18 Apr 2019


Article type: Paper
DOI: 10.1039/C9NJ00347A
New J. Chem., 2019,43, 7941-7949

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    Energy framework approach to the supramolecular reactions: interplay of the secondary bonding interaction in Ph2E2 (E = Se, Te)/p-I-C6F4-I co-crystals

    Y. V. Torubaev, D. K. Rai, I. V. Skabitsky, S. Pakhira and A. Dmitrienko, New J. Chem., 2019, 43, 7941
    DOI: 10.1039/C9NJ00347A

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