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Issue 8, 2019
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3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

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Abstract

[Co(C2B9H11)2], analogs to metallocene, can be readily synthesised in high yield by a fast and clean solvent-free reaction of [HNMe3][C2B9H12] with CoCl2·xH2O. This innovative approach, applied to both ortho and meta isomers, yields the desired structures by simply heating the solid compounds to high temperature for a very short time.

Graphical abstract: 3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

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Supplementary files

Article information


Submitted
17 Dec 2018
Accepted
18 Mar 2019
First published
20 Mar 2019

This article is Open Access

Green Chem., 2019,21, 1925-1928
Article type
Communication

3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

I. Bennour, A. M. Cioran, F. Teixidor and C. Viñas, Green Chem., 2019, 21, 1925
DOI: 10.1039/C8GC03943G

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