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Issue 8, 2019
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3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

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Abstract

[Co(C2B9H11)2], analogs to metallocene, can be readily synthesised in high yield by a fast and clean solvent-free reaction of [HNMe3][C2B9H12] with CoCl2·xH2O. This innovative approach, applied to both ortho and meta isomers, yields the desired structures by simply heating the solid compounds to high temperature for a very short time.

Graphical abstract: 3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

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Publication details

The article was received on 17 Dec 2018, accepted on 18 Mar 2019 and first published on 20 Mar 2019


Article type: Communication
DOI: 10.1039/C8GC03943G
Green Chem., 2019,21, 1925-1928
  • Open access: Creative Commons BY-NC license
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    3,2,1 and stop! An innovative, straightforward and clean route for the flash synthesis of metallacarboranes

    I. Bennour, A. M. Cioran, F. Teixidor and C. Viñas, Green Chem., 2019, 21, 1925
    DOI: 10.1039/C8GC03943G

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