Issue 1, 2019

How transport layer properties affect perovskite solar cell performance: insights from a coupled charge transport/ion migration model

Abstract

The effects of transport layers on perovskite solar cell performance, in particular anomalous hysteresis, are investigated. A model for coupled ion vacancy motion and charge transport is formulated and solved in a three-layer planar perovskite solar cell. Its results are used to demonstrate that the replacement of standard transport layer materials (spiro-OMeTAD and TiO2) by materials with lower permittivity and/or doping leads to a shift in the scan rates at which hysteresis is most pronounced to rates higher than those commonly used in experiment. These results provide a cogent explanation for why organic electron transport layers can yield seemingly “hysteresis-free” devices but which nevertheless exhibit hysteresis at low temperature. In these devices the decrease in ion vacancy mobility with temperature compensates for the increase in hysteresis rate with use of low permittivity/doping organic transport layers. Simulations are used to classify features of the current–voltage curves that distinguish between cells in which charge carrier recombination occurs predominantly at the transport layer interfaces and those where it occurs predominantly within the perovskite. These characteristics are supplemented by videos showing how the electric potential, electronic and ionic charge profiles evolve across a planar perovskite solar cell during a current–voltage scan. Design protocols to mitigate the possible effects of high ion vacancy distributions on cell degradation are discussed. Finally, features of the steady-state potential profile for a device held near the maximum power point are used to suggest ways in which interfacial recombination can be reduced, and performance enhanced, via tuning transport layer properties.

Graphical abstract: How transport layer properties affect perovskite solar cell performance: insights from a coupled charge transport/ion migration model

Supplementary files

Article information

Article type
Paper
Submitted
31 May 2018
Accepted
07 Dec 2018
First published
21 Dec 2018
This article is Open Access
Creative Commons BY license

Energy Environ. Sci., 2019,12, 396-409

How transport layer properties affect perovskite solar cell performance: insights from a coupled charge transport/ion migration model

N. E. Courtier, J. M. Cave, J. M. Foster, A. B. Walker and G. Richardson, Energy Environ. Sci., 2019, 12, 396 DOI: 10.1039/C8EE01576G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements