Jump to main content
Jump to site search
Publishing
Advanced

Issue 47, 2019
Previous Article Next Article

A triple-triangle cluster derived from a simple tridentate ligand†

Takuya Shiga, ORCID logo *a   Natsumi Okawaa  and  Hiroki Oshio ORCID logo ab  
Author affiliations

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
E-mail: shiga@chem.tsukuba.ac.jp

b State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., 116024 Dalian, P. R. of China

Abstract

The heptanuclear ferric cluster, [FeIII7(O)6(HL)5(H2L)(H2O)8](BF4)4 (H2L = 2,6-bis(1,5-diphenyl-1H-pyrazol-3-yl)pyridine), was synthesized by the reaction of the planar tridentate ligand H2L with iron(II) tetrafluoroborate hexahydrate. The cluster has a corner-shared triple-triangle core structure connected by three μ-O atoms, and it has a spin-frustrated ferrimagnetic spin ground state of S = 19/2.

Graphical abstract: A triple-triangle cluster derived from a simple tridentate ligand

Back to tab navigation
Download options Please wait...

Supplementary files

Article information

https://doi.org/10.1039/C9DT03232K
Submitted
08 Aug 2019
Accepted
29 Oct 2019
First published
05 Nov 2019
Dalton Trans., 2019,48, 17437-17440
Article type
Communication
Permissions
Request permissions

A triple-triangle cluster derived from a simple tridentate ligand

T. Shiga, N. Okawa and H. Oshio, Dalton Trans., 2019, 48, 17437
DOI: 10.1039/C9DT03232K

If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Go to our Instructions for using Copyright Clearance Center page for details.

Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.
  • For reproduction of material from PCCP:
    Reproduced from Ref. XX with permission from the PCCP Owner Societies.
  • For reproduction of material from PPS:
    Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.
  • For reproduction of material from all other RSC journals and books:
    Reproduced from Ref. XX with permission from The Royal Society of Chemistry.

If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

In all cases the Ref. XX is the XXth reference in the list of references.

If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC
  • For reproduction of material from PCCP:
    [Original citation] - Reproduced by permission of the PCCP Owner Societies
  • For reproduction of material from PPS:
    [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC
  • For reproduction of material from all other RSC journals:
    [Original citation] - Reproduced by permission of The Royal Society of Chemistry

If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Social activity

Search articles by author

Spotlight

Advertisements