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Issue 46, 2019
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Site-selective cation–π interaction as a way of selective recognition of the caesium cation using sumanene-functionalized ferrocenes

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Abstract

The first sumanene–ferrocene probes for efficient and selective caesium cation (Cs+) recognition are reported. The working mechanism of the sumanene moiety as the sensing unit was based on the site-selective cation–π interaction in its neutral state. The interactions with Cs+ were characterized by high association constant values together with low limits of detection.

Graphical abstract: Site-selective cation–π interaction as a way of selective recognition of the caesium cation using sumanene-functionalized ferrocenes

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Publication details

The article was received on 03 Aug 2019, accepted on 23 Sep 2019 and first published on 23 Sep 2019


Article type: Communication
DOI: 10.1039/C9DT03162F
Dalton Trans., 2019,48, 17147-17152

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    Site-selective cation–π interaction as a way of selective recognition of the caesium cation using sumanene-functionalized ferrocenes

    A. Kasprzak and H. Sakurai, Dalton Trans., 2019, 48, 17147
    DOI: 10.1039/C9DT03162F

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