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Issue 39, 2019
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Aggregation of Au(i)-complexes on amorphous substrates governed by aurophilicity

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Abstract

In single crystals of 2-naphthylisonitrile–gold(I)-halide (halide = Cl, Br, I) complexes, Au⋯Au distances are found to be significantly shorter than twice the van der Waals radius, indicating attractive interactions between gold atoms in adjacent molecules. In the particular case of the studied 2-naphthylisonitrile–gold(I) complexes, homodimers are the common structural motifs, in which the linearly coordinated gold exhibits a crossed swords arrangement with the Au atoms of two molecules being at the intersection point. The crossed swords motif is preserved upon physical vapour deposition of both the chlorine and bromine derivatives on amorphous substrates like glass and glassy carbon. The determined activation energies of desorption for the chlorine (0.9 eV) and the bromine (1.2 eV) derivative are comparable to that of unsubstituted naphthalene. Using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and ion scattering (RBS), we confirmed the chemical integrity of the molecules in thin films and revealed the orientation of the crossed swords dimers with respect to the substrate surface.

Graphical abstract: Aggregation of Au(i)-complexes on amorphous substrates governed by aurophilicity

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Publication details

The article was received on 25 Jul 2019, accepted on 07 Sep 2019 and first published on 09 Sep 2019


Article type: Paper
DOI: 10.1039/C9DT03049B
Dalton Trans., 2019,48, 14712-14723
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    Aggregation of Au(I)-complexes on amorphous substrates governed by aurophilicity

    P. Gründlinger, M. Györök, S. Wolfmayr, T. Breuer, D. Primetzhofer, B. Bruckner, U. Monkowius and T. Wagner, Dalton Trans., 2019, 48, 14712
    DOI: 10.1039/C9DT03049B

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