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Issue 29, 2019
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The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

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Abstract

The first ThIV/ThIII redox couple values have been determined experimentally using cyclic voltammetry (CV), which has been facilitated by the use of [nBu4N][BPh4] as a supporting electrolyte in THF. Th(IV) and Th(III) metallocene compounds have been studied and their redox couple values are in the range of −2.96 V to −3.32 V vs FeCp2+/0.

Graphical abstract: The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

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Supplementary files

Article information


Submitted
11 Apr 2019
Accepted
04 Jun 2019
First published
05 Jun 2019

Dalton Trans., 2019,48, 10782-10784
Article type
Communication

The experimental determination of Th(IV)/Th(III) redox potentials in organometallic thorium complexes

C. J. Inman and F. G. N. Cloke, Dalton Trans., 2019, 48, 10782
DOI: 10.1039/C9DT01553A

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