The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Tomohiro Sugahara; Takahiro Sasamori; Norihiro Tokitoh

doi:10.1039/C9DT01322A

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative†

Tomohiro Sugahara,^a Takahiro Sasamori

*^b and Norihiro Tokitoh

^ac

Author affiliations

* Corresponding authors

^a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

^b Graduate School of Natural Sciences, Nagoya City University, Nagoya, Aichi 467-8501, Japan
E-mail: sasamori@nsc.nagoya-cu.ac.jp

^c Integrated Research Consortium on Chemical Sciences, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

Abstract

A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.

This article is part of the themed collection: Inorganic chemistry of the p-block elements

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Article information

https://doi.org/10.1039/C9DT01322A

Submitted

28 Mar 2019

Accepted

17 May 2019

First published

17 May 2019

Download Citation

Dalton Trans., 2019,48, 9053-9056

Article type

Communication

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The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

T. Sugahara, T. Sasamori and N. Tokitoh, Dalton Trans., 2019, 48, 9053

DOI: 10.1039/C9DT01322A

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The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative†

Abstract

Supplementary files

Article information

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

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